Kategorie

减少/脱除 CO

可显著降低CO含量的先进催化剂。

该催化剂技术进一步扩展了使用蜂窝结构减少CO的优势,在工业应用中以其卓越的效率和可持续性脱颖而出。经过验证的设计不仅优化了化学反应的表面积,还确保了均匀的流量分布,最大限度地降低了压降,增强了气体与催化剂的接触。这显著提高了CO转化率,减少了有害污染物的排放,并有助于行业超越环境合规性。

蜂窝型催化剂的耐用性和结构完整性有助于延长其使用寿命和可靠性,减少停产时间和维护成本。此外,这种催化剂设计能够适应各种工业环境,提供了安装和操作的灵活性。反应效率的提高降低了运行能耗,实现能源节约。

主要用途:

  • 工业排放控制:有效降低制造过程废气中的CO含量。
  • 能源生产:应用于发电厂和其他发电设施,以尽量减少CO排放。
  • 化工制造:控制CO为副产品的化学生产中的排放。

 

这些应用突出了蜂窝型催化剂的多功能性和在解决行业中环境问题方面的关键作用,使其成为可持续工业实践的基础技术。

Introduction and Background: Catalytic Off-Gas Treatment in Metallurgical Processes

Catalytic conversion of carbon monoxide (CO) and volatile organic compounds (VOCs) in metallurgical off-gases presents several challenges. These include the presence of catalyst poisons (e.g., arsenic, lead, hydrogen fluoride), high dust loads, and fluctuating inlet temperatures.

 

One specific challenge—the variable and often undefined concentrations of sulfur dioxide (SO₂) in the gas stream— is mitigated by increasing the inlet temperature. The non specified and changing concentrations of SO2 in the gas stream is tackled by the increase of the inlet temperature to the catalyst, which is positioned on top of a hot gas filter system keep the temperature loss and dust load minimal (see Fig. 1).

The Catalytic Performance

a) The Inlet Temperature

As a rule of thumb Arrhenius´ law states that reaction rates shall double every 10 °C of temperature-increase. This chemical law is employed to enhance the catalytic activity of overall system.

b) The Catalyst Volume

The calculation of the catalyst volume plays an essential role by the efficient oxidation. Furthermore, regularly renewal of catalysts is advised. Older catalyst can stay and serve as a first-contact, sacrificial layer to absorb poisons and prolong the activity of fresh material.

All Non-Ferrous Metallurgy Companies can benefit from this process reducing their emissions and cutting the CAPEX and OPEX!

This process demonstrates the feasibility of catalytic off-gas treatment for CO and TVOC oxidation in non-ferrous metallurgical processes.

The second way to increase the reliability of the catalytic turnover is to oversize the catalyst volume to tackle possible poisoning or aging of the catalyst.

P&Ps catalyst experts can recommend a service interval for catalytic layers based on the actual process gas composition and plant operation.